PARTIAL OXIDATION OF OLEFINS BY MOLECULAR-OXYGEN CATALYZED BY (ALUMINA)RH(O2) .2.

被引：6

作者：

SCHWARTZ, J

MCMILLAN, JW

FISCHER, HE

机构：

[1] Department of Chemistry, Princeton University, Princeton

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1992年 / 74卷 / 1-3期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0304-5102(92)80261-E

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Selective partial oxidation of a series of olefins was accomplished using molecular oxygen, catalyzed by (alumina)Rh(O2). Ketones were the major products; no allylic oxidation was noted, and little combustion or double-bond cleavage was observed. A mechanism involving a carbocationic intermediate is proposed; competitive trapping to either coordinated glycolate or coordinated epoxide is suggested to give the observed ketonic products.

引用

页码：443 / 450

页数：8

共 21 条

[1] RHODIUM-CATALYZED C,C-DOUBLE BOND-CLEAVAGE BY MOLECULAR-OXYGEN [J].