3,4-DIHYDROXY-7,8-DIHYDRO-BETA-IONONE BETA-D-GLUCOPYRANOSIDE - NATURAL PRECURSOR OF 2,2,6,8-TETRAMETHYL-7,11-DIOXATRICYCLO[6.2.1.0(1,6)]UNDEC-4-ENE (RIESLING ACETAL) AND 1,1,6-TRIMETHYL-1,2-DIHYDRONAPHTHALENE IN RED CURRANT (RIBES-RUBRUM L) LEAVES

被引：24

作者：

HUMPF, HU ^{[1
]}

WINTERHALTER, P ^{[1
]}

SCHREIER, P ^{[1
]}

机构：

[1] UNIV WURZBURG, LEHRSTUHL LEBENSMITTELCHEM, HUBLAND, W-8700 WURZBURG, GERMANY

来源：

JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY | 1991年 / 39卷 / 10期

关键词：

D O I：

10.1021/jf00010a029

中图分类号：

S [农业科学];

学科分类号：

09 ;

摘要：

A precursor of 2,2,6,8-tetramethyl-7,11-dioxatricyclo[6.2.1.0(1,6)]undec-4-ene (Riesling acetal) and 1,1,6-trimethyl-1,2-dihydronaphthalene (TDN),3,4-dihydroxy-7,8-dihydro-beta-ionone-beta-D-glucopyranoside, was isolated from red currant (Ribes rubrum L.) leaves. The steps of isolation comprised retention of the glycosides on Amberlite XAD-2 resin and subsequent prefractionation of the methanolic eluate by rotation locular countercurrent chromatography (RLCC). After acetylation and liquid chromatographic purification, characterization was made by means of LC-MS and NMR analyses.

引用

页码：1833 / 1835

页数：3

共 11 条

[1]

GULDNER A, 1991, UNPUB J AGR FOOD CHE

[2] THE AROMA OF GRAPES .1. EXTRACTION AND DETERMINATION OF FREE AND GLYCOSIDICALLY BOUND FRACTIONS OF SOME GRAPE AROMA COMPONENTS [J].

GUNATA, YZ ;

BAYONOVE, CL ;

BAUMES, RL ;

CORDONNIER, RE .

JOURNAL OF CHROMATOGRAPHY, 1985, 331 (01) :83-90

[3] 3-HYDROXY-RETRO-ALPHA-IONOL - A NATURAL PRECURSOR OF ISOMERIC EDULANS IN PURPLE PASSION-FRUIT (PASSIFLORA-EDULIS-SIMS) [J].

HERDERICH, M ;

WINTERHALTER, P .

JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 1991, 39 (07) :1270-1274

[4] IONONE AND LIGNAN GLYCOSIDES FROM EPIMEDIUM-DIPHYLLUM [J].

MIYASE, T ;

UENO, A ;

TAKIZAWA, N ;

KOBAYASHI, H ;

OGUCHI, H .

PHYTOCHEMISTRY, 1989, 28 (12) :3483-3485

[5] STRUCTURE AND SYNTHESIS OF 2 NOVEL IONONE-TYPE COMPOUNDS IDENTIFIED IN QUINCE BRANDY (CYDONIA-OBLONGA MIL) [J].

NAF, R ;

VELLUZ, A ;

DECORZANT, R ;

NAF, F .

TETRAHEDRON LETTERS, 1991, 32 (06) :753-756

[6] ISOLATION OF VOLATILE COMPONENTS FROM A MODEL SYSTEM [J].

SCHULTZ, TH ;

FLATH, RA ;

MON, TR ;

EGGLING, SB ;

TERANISHI, R .

JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 1977, 25 (03) :446-449

[7] RAPID CHROMATOGRAPHIC TECHNIQUE FOR PREPARATIVE SEPARATIONS WITH MODERATE RESOLUTION [J].

STILL, WC ;

KAHN, M ;

MITRA, A .

JOURNAL OF ORGANIC CHEMISTRY, 1978, 43 (14) :2923-2925

[8]

WINTERHALTER P, 1990, CHEM IND-LONDON, P463

[9] 1,1,6-TRIMETHYL-1,2-DIHYDRONAPHTHALENE (TDN) FORMATION IN WINE .1. STUDIES ON THE HYDROLYSIS OF 2,6,10,10-TETRAMETHYL-1-OXASPIRO[4.5]DEC-6-ENE-2,8-DIOL RATIONALIZING THE ORIGIN OF TDN AND RELATED C-13 NORISOPRENOIDS IN RIESLING WINE [J].

WINTERHALTER, P .

JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 1991, 39 (10) :1825-1829

[10]

WINTERHALTER P, 1989, ACS SYM SER, V409, P320

← 1 2 →