3,4-DIHYDROXY-7,8-DIHYDRO-BETA-IONONE BETA-D-GLUCOPYRANOSIDE - NATURAL PRECURSOR OF 2,2,6,8-TETRAMETHYL-7,11-DIOXATRICYCLO[6.2.1.0(1,6)]UNDEC-4-ENE (RIESLING ACETAL) AND 1,1,6-TRIMETHYL-1,2-DIHYDRONAPHTHALENE IN RED CURRANT (RIBES-RUBRUM L) LEAVES

被引：24

作者：

HUMPF, HU ^{[1
]}

WINTERHALTER, P ^{[1
]}

SCHREIER, P ^{[1
]}

机构：

[1] UNIV WURZBURG, LEHRSTUHL LEBENSMITTELCHEM, HUBLAND, W-8700 WURZBURG, GERMANY

来源：

JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY | 1991年 / 39卷 / 10期

关键词：

D O I：

10.1021/jf00010a029

中图分类号：

S [农业科学];

学科分类号：

09 ;

摘要：

A precursor of 2,2,6,8-tetramethyl-7,11-dioxatricyclo[6.2.1.0(1,6)]undec-4-ene (Riesling acetal) and 1,1,6-trimethyl-1,2-dihydronaphthalene (TDN),3,4-dihydroxy-7,8-dihydro-beta-ionone-beta-D-glucopyranoside, was isolated from red currant (Ribes rubrum L.) leaves. The steps of isolation comprised retention of the glycosides on Amberlite XAD-2 resin and subsequent prefractionation of the methanolic eluate by rotation locular countercurrent chromatography (RLCC). After acetylation and liquid chromatographic purification, characterization was made by means of LC-MS and NMR analyses.

引用

页码：1833 / 1835

页数：3