ENANTIOSELECTIVE SYNTHESIS OF THE METHYLENECYCLOPROPANE DERIVATIVE RELATED TO HYPOGLYCINE, FROM MALIC-ACID

被引：26

作者：

ACHMATOWICZ, B ^{[1
]}

KABAT, MM ^{[1
]}

KRAJEWSKI, J ^{[1
]}

WICHA, J ^{[1
]}

机构：

[1] POLISH ACAD SCI,INST ORGAN CHEM,UL KASPRZAKA 44,PL-01224 WARSAW,POLAND

来源：

TETRAHEDRON | 1992年 / 48卷 / 46期

关键词：

D O I：

10.1016/S0040-4020(01)89048-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Synthesis of (S)-methylenecyclopropaneacetic acid starting from L-(-)-malic acid, via (2S)-O-tert-butyldimethylsilyl-1,2-epoxybutan-4-ol and 1-O-tert-butyldiphenylsilyl-5-benzenesulfonyl-6-trimethylsilylhexane-1,3-diols as the key intermediates, is described.

引用

页码：10201 / 10210

页数：10

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