MOSSBAUER SPECTROSCOPIC STUDY OF PRUSSIAN BLUE FROM DIFFERENT PROVENANCES

被引：40

作者：

REGUERA, E

FERNANDEZBERTRAN, J

DAGO, A

DIAZ, C

机构：

[1] Centro Nacional de Investigaciones Cientificas, Havana

来源：

HYPERFINE INTERACTIONS | 1992年 / 73卷 / 3-4期

关键词：

D O I：

10.1007/BF02418604

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

Ferric ferrocyanides synthesized from different sources of ferric cations and ferrocyanide anions and those derived from ferrous ferricyanide, ferrous ferrocyanide and ferric ferricyanide have been studied using Mossbauer and XRD techniques. Structural information of the effect of the provenance on the properties of the final compound is obtained. Significant correlations between isomer shift and quadrupole splitting of inner and outer iron cations have been observed.

引用

页码：295 / 308

页数：14

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