2H,5H-BENZO[1,2-B/4,5-B']BISTHIETE - A HIGHLY REACTIVE BISDIENE SYSTEM

被引：17

作者：

MEIER, H

MAYER, A

机构：

[1] Institut für Organische Chemie, Universität Mainz, D-55099

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 04期

关键词：

D O I：

10.1002/anie.199404651

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound 2 is a rigid molecule with two potential 1,3‐diene units. It was synthesized in three steps from the diester 1. The successive opening of the four‐membered rings of 2 enables the construction of linear annelated ring systems and band structures; for example, the reaction with dimethyl acetylenedicarboxylate leads to the tricycle 3. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

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页码：465 / 467

页数：3

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