THE ROTATIONALLY RESOLVED G0(U)+[-A0(G)+ ELECTRONIC-SPECTRUM OF THE (HG-202)(2) EXCIMER

被引：12

作者：

KEDZIERSKI, W

SUPRONOWICZ, J

CZAJKOWSKI, A

HINEK, MJ

ATKINSON, JB

KRAUSE, L

机构：

[1] Department of Physics, University of Windsor, Windsor

来源：

CHEMICAL PHYSICS LETTERS | 1994年 / 218卷 / 04期

关键词：

D O I：

10.1016/0009-2614(93)E1487-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Isotopically pure Hg-202 vapor, contained in a quartz cell, was irradiated with frequency-doubled 5140 angstrom output from an Ar+ laser, which caused the formation of Hg2A0g+/- excimer molecules by photoassociation. Simultaneous probe radiation from a ring dye laser scanned over a range 5400-6000 angstrom, produced the G0u+<--A0g+ excitation spectrum which consists of several hundred well-resolved rotational components that have not been previously observed. Two vibronic bands were subjected to a rotational analysis which yielded spectroscopic constants that are compared with some previously reported values.

引用

页码：314 / 319

页数：6

共 13 条

[1] ABINITIO CALCULATIONS OF POTENTIAL-ENERGY CURVES OF HG2 AND TLHG [J].