DETECTION OF ATOMIC OXYGEN IN FLAMES BY ABSORPTION-SPECTROSCOPY

被引:12
作者
CHESKIS, S [1 ]
KOVALENKO, SA [1 ]
机构
[1] RUSSIAN ACAD SCI,INST CHEM PHYS,MOSCOW 117334,RUSSIA
来源
APPLIED PHYSICS B-LASERS AND OPTICS | 1994年 / 59卷 / 05期
关键词
D O I
10.1007/BF01082398
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
The absolute concentration of atomic oxygen in an atmospheric pressure hydrogen/air flame has been measured using Intracavity Laser Spectroscopy (ICLS) based on a dye laser pumped by an argon-ion laser. Absorptions at the highly forbidden transitions at 630.030 nm and 636.380 nm were observed at an equivalent optical length of up to 10 km. The relatively low intensity of the dye laser avoids photochemical interferences that are inherent to some other methods for detecting atomic oxygen. The detection sensitivity is about 6 x 10(14) atom/cm(3) and can be improved with better flame and laser stabilization.
引用
收藏
页码:543 / 546
页数:4
相关论文
共 20 条
[1]   2-PHOTON EXCITATION OF ATOMIC OXYGEN IN A FLAME [J].
ALDEN, M ;
EDNER, H ;
GRAFSTROM, P ;
SVANBERG, S .
OPTICS COMMUNICATIONS, 1982, 42 (04) :244-246
[2]  
BAEV VM, 1978, ZH EKSP TEOR FIZ, V47, P21
[3]  
BRUKOV MG, 1991, J PHYS IV, V1, P485
[4]  
CAMPARGUE A, 1990, SPECTROCHIM ACTA REV, V13, P69
[5]   METHANE OVERTONE ABSORPTION BY INTRACAVITY LASER SPECTROSCOPY [J].
CVIJIN, PV ;
OBRIEN, JJ ;
ATKINSON, GH ;
WELLS, WK ;
LUNINE, JI ;
HUNTEN, DM .
CHEMICAL PHYSICS LETTERS, 1989, 159 (04) :331-336
[6]   LASER-INDUCED FLUORESCENCE MEASUREMENT OF OXYGEN-ATOMS ABOVE A CATALYTIC COMBUSTOR SURFACE [J].
DYER, MJ ;
PFEFFERLE, LD ;
CROSLEY, DR .
APPLIED OPTICS, 1990, 29 (01) :111-118
[7]   PHOTOCHEMICAL EFFECTS IN 2-PHOTON-EXCITED FLUORESCENCE DETECTION OF ATOMIC OXYGEN IN FLAMES [J].
GOLDSMITH, JEM .
APPLIED OPTICS, 1987, 26 (17) :3566-3572
[8]   RESONANT MULTIPHOTON OPTOGALVANIC DETECTION OF ATOMIC OXYGEN IN FLAMES [J].
GOLDSMITH, JEM .
JOURNAL OF CHEMICAL PHYSICS, 1983, 78 (03) :1610-1611
[9]  
GOLDSMITH JEM, 1984, 20TH S INT COMB PITT, P1331
[10]   DETECTION OF ATOMIC OXYGEN BY INTRA-CAVITY SPECTROSCOPY [J].
HARRIS, SJ ;
WEINER, AM .
OPTICS LETTERS, 1981, 6 (03) :142-144