ADSORPTION OF ETHOXYLATED SULFONATES ON KAOLINITE AND ALUMINA

被引:22
作者
VISWANATHAN, KV [1 ]
SOMASUNDARAN, P [1 ]
机构
[1] COLUMBIA UNIV,HENRY KRUMB SCH MINES,SCH ENGN & APPL SCI,NEW YORK,NY 10027
来源
COLLOIDS AND SURFACES | 1987年 / 26卷
关键词
ALUMINA - LIQUIDS - Surface Tension - OIL WELL PRODUCTION - Flooding - SODIUM COMPOUNDS;
D O I
10.1016/0166-6622(87)80104-X
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Ethoxylated surfactants have been reported to show improved interfacial tension and calcium tolerance properties, even though the mechanism by which ethoxylates influence interfacial phenomena are not completely understood. The impurities present in technical grade ethoxylated sulfonates place a major hurdle in studying this type of surfactants. A technique based on flash chromatography was therefore developed for separating them and the collected fractions were characterized using HPLC and NMR. Adsorption studies showed the nonionic impurities to enhance the adsorption of as received and purified ethoxylated sulfonate on alumina in the premicellar region. This work is pertinent to micellar flooding in petroleum.
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页码:19 / 41
页数:23
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