The polymerization of vinyl monomers in the presence of surface active agents. I. The polymerization of methyl methacrylate

被引：20

作者：

Asahara, Teruzo ^{[1
]}

Seno, Manabu ^{[1
]}

Shiraishi, Shinsaku ^{[1
]}

Arita, Yoshikazu ^{[1
]}

机构：

[1] Univ Tokyo, Inst Ind Sci, Minato Ku, Tokyo, Japan

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1970年 / 43卷 / 12期

关键词：

D O I：

10.1246/bcsj.43.3895

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Methyl methacrylate polymerized in the presence of a surface active agent in an aqueous system without any ordinary initiators. Anionic surface active agents, such as sodium tetra-propylenebenzenesulfon ate and sodium 2-dodecylbenzenesulfonate, markedly effected the polymerization of methyl methacrylate in the presence of water. The polymerization was inhibited by adding hydroquinone to the reaction system and was also affected adversely by oxygen. Water as a reaction medium was found to be indispensable. The polymerization in organic solvents afforded hardly any polymeric products.

引用

页码：3895 / 3898

页数：4