REACTION OF BIS[TRICARBONYL(TRIPHENYLPHOSPHINE)IRIDIUM], IR2(CO)6(PPH3)2, WITH DIAZONIUM SALTS

被引：4

作者：

ANGOLETTA, M ^{[1
]}

CAGLIO, G ^{[1
]}

机构：

[1] CNR,CTR STUDIO SINTESI & STRUTTURA COMPOSTI MET TRANSIZIONE,I-20133 MILAN,ITALY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 182卷 / 03期

关键词：

D O I：

10.1016/S0022-328X(00)84826-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of Ir2(CO)6(PPh3)2 with p-substituted aryldiazoniurn salts gives the o-metalated complexes [Ir(CO)2(NHNC6H3R) (PPh3)]22+ 2BF4-. These react with KOH in ethanol to give the deprotonated derivatives, and with halogens to give halogenated derivatives by cleavage of the carbonmetal bond. © 1979.

引用

页码：425 / 430

页数：6

共 4 条

[1]

ANGOLETTA M, 1976, J ORGANOMETAL CHEM, V2, P219

[2] EXTENSION OF NITROSYL-ARYLDIAZO ANALOGY - STRUCTURE OF AN ARYLDIAZO GROUP COORDINATED TO RHODIUM IN A DOUBLY BENT FASHION [J].

GAUGHAN, AP ;

HAYMORE, BL ;

IBERS, JA ;

MYERS, WH ;

NAPPIER, TE ;

MEEK, DW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1973, 95 (20) :6859-6861

[3] ARYLDIAZENATO-COMPLEXS AND ARYLDIAZENE-COMPLEXES - SOME ORTHOMETALLATED COMPOUNDS DERIVED FROM REACTIONS OF DIAZONIUM IONS WITH CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM [J].

GILCHRIST, AB ;

SUTTON, D .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1977, (07) :677-682

[4] PREPARATION AND REACTIONS OF BIS[TRICARBONYL(TRIPHENYLPHOSPHINE)IRIDIUM] [J].

MALATESTA, L ;

ANGOLETT.M ;

CAGLIO, G .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1974, 73 (02) :265-275

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