MARINE NATURAL-PRODUCTS .15. POLYHALOGENATED CYCLIC MONOTERPENES FROM THE RED ALGA PLOCAMIUM-CARTILAGINEUM OF ANTARCTICA

被引：47

作者：

STIERLE, DB ^{[1
]}

SIMS, JJ ^{[1
]}

机构：

[1] UNIV CALIF RIVERSIDE,RIVERSIDE,CA 92521

来源：

TETRAHEDRON | 1979年 / 35卷 / 10期

关键词：

D O I：

10.1016/0040-4020(79)80051-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Examination of the red alga Plocamium cartilagineum (L.) Dixon collected along the Antarctic Peninsula yielded several new cyclic halogenated monoterpenes. The structures of a 2,4-dichloro-trans-1-chloro-vinyl-1-methyl-5-methylene-cyclohexane, a 2-chloro-4-bromo-trans-1-chlorovinyl-1-methyl-5-methylene-cyclohexane, a 2-chloro-trans-1-chlorovinyl-1-methyl-5-chloromethyl-4-cyclohexene, and a 2,5-dichloro-4-bromo-trans-1-chlorovinyl-1-methyl-5-bromomethyl-cyclohexane are described. The structures were determined by spectroscopic methods and chemically related to the halogenated monoterpene violacene. © 1979.

引用

页码：1261 / 1265

页数：5

共 16 条

[1] CLEAVAGE OF BONDS BY LOW VALENT TRANSITION METAL IONS - HOMOGENEOUS REDUCTION OF ALKYL HALIDES BY CHROMOUS SULFATE [J].