FLASH VACUUM THERMOLYSIS OF BIPHENYLENE AND DIPHENIC ANHYDRIDE - FORMATION OF 6B,7,10,10A-TETRAHYDRO-AS-INDACENO[1,8-JKL]FLUORANTHENE - EVIDENCE FOR THE INTERMEDIACY OF AS-INDACENE ON THE C12H8 POTENTIAL-ENERGY SURFACE

被引：18

作者：

WIERSUM, UE ^{[1
]}

JENNESKENS, LW ^{[1
]}

机构：

[1] UNIV UTRECHT,DEBYE INST,DEPT PHYS ORGAN CHEM,3584 CH UTRECHT,NETHERLANDS

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 41期

关键词：

D O I：

10.1016/0040-4039(93)88119-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Flash Vacuum Thermolysis (FVT) of biphenylene (1) and of diphenic anhydride (2) at 900-degrees-C gave acenaphtylene (10), exo- and endo-6b,7,10,10a-tetrahydro-as-indaceno[1,8-jkl]fluoranthene (11) in high yield. The isolation of compound 11 provides evidence for the occurrence of the anti-aromatic as-indacene (8) on the C12H8 potential energy surface

引用

页码：6615 / 6618

页数：4

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