ON THE ELECTRONIC ORIGIN OF THE DIFFERENCE IN ACIDITY BETWEEN FORMIC-ACID AND ETHANOL

被引：7

作者：

GODFREY, M

机构：

[1] Department of Chemistry, The University, Southampton

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 36期

关键词：

D O I：

10.1016/S0040-4039(00)97837-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The greater acidity of formic acid than of ethanol is interpreted in terms of a coupled polarization and charge transfer effect rather than a resonance effect or a field/inductive effect. The wider significance of this interpretation is briefly discussed. The greater acidity of HCOOH than of CH3CH2OH is interpreted in terms of a coupled polarization and charge transfer effect rather than a resonance effect or a field/inductive effect. The wider significance of this interpretation is briefly discussed. © 1990.

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页码：5181 / 5184

页数：4

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