KINETIC STUDIES ON THE NUCLEOPHILIC-ADDITION TO DOUBLE-BONDS .1. ADDITION OF AMINES TO ELECTROPHILIC CARBON-CARBON DOUBLE-BONDS

被引：49

作者：

SCHREIBER, B ^{[1
]}

MARTINEK, H ^{[1
]}

WOLSCHANN, P ^{[1
]}

SCHUSTER, P ^{[1
]}

机构：

[1] VIENNA UNIV,INST THEORET CHEM STRAHLENCHEM,A-1090 VIENNA,AUSTRIA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1979年 / 101卷 / 16期

关键词：

D O I：

10.1021/ja00510a046

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Kinetic and thermodynamic data are reported for the primary elementary step of nucleophilic addition to polar carbon-carbon double bonds in aprotic solvents (acetonitrile and chloroform). As nucleophiles primary, secondary, and tertiary amines were applied. The rapid reaction techniques used are stopped-flow (SF) and temperature-jump (TJ) relaxation. © 1979, American Chemical Society. All rights reserved.

引用

页码：4708 / 4713

页数：6

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