INTERFERENCE BETWEEN INTRA-MANIFOLD AND INTER-MANIFOLD COUPLINGS IN RESONANCE RAMAN-SPECTRA OF METALLOPORPHYRINS

被引：27

作者：

ZGIERSKI, MZ

SHELNUTT, JA

PAWLIKOWSKI, M

机构：

[1] BELL TEL LABS INC,MURRAY HILL,NJ 07974

[2] JAGIELLONIAN UNIV,DEPT THEORET CHEM,PL-30060 CRACOW,POLAND

来源：

CHEMICAL PHYSICS LETTERS | 1979年 / 68卷 / 2-3期

关键词：

D O I：

10.1016/0009-2614(79)87197-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Anomalous intensity ratios in the excitation profiles of vibronically active fundamentals in the Q-band of porphyrins are shown to be due to interference between intramanifold (Jahn-Teller) coupling with the Q and B bands, intermanifold (Herzberg-Teller) coupling between the Q and B bands, and electronic configuration interaction between the one-electron representations of the corresponding excited states. © 1979.

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页码：262 / 266

页数：5

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