A PORPHYRIN RIGIDLY LINKED TO ONE OR 2 TERPYRIDINE CHELATES USED AS ASSEMBLING SUBUNITS

被引：34

作者：

COLLIN, JP

HEITZ, V

SAUVAGE, JP

机构：

[1] Laboratoire de Chimie Organo-Minérale, associé au CNRS, Faculté de Chimie, 67008 Strasbourg, 1, rue Blaise Pascal

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 42期

关键词：

D O I：

10.1016/S0040-4039(00)79442-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The "2+2" condensation of (3,3'-diethyl-4,4'-dimethyl-2,2'-dipyrrolyl) methane with an aromatic aldehyde bearing a 2,2',6',2"-terpyridine (terpy) ligand leads after oxidation of the intermediate porphyrinogen to a porphyrin bearing two terpy chelates disposed in an antiparallel geometry. If the same reaction is carried out in the presence of a benzaldehyde derivative, the mono-terpy porphyrin is also obtained.

引用

页码：5977 / 5980

页数：4

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