(1R)-MENTHOXYMETHYL ETHER, A CHIRAL OH PROTECTING GROUP AND ITS USE IN THE MEASUREMENT OF ENANTIOMERIC EXCESS

被引：9

作者：

DAWKINS, D ^{[1
]}

JENKINS, PR ^{[1
]}

机构：

[1] UNIV LEICESTER,DEPT PHYS,LEICESTER LE1 7RH,ENGLAND

来源：

TETRAHEDRON-ASYMMETRY | 1992年 / 3卷 / 07期

关键词：

D O I：

10.1016/S0957-4166(00)82177-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The protection of a range of chiral alcohols with chloromethyl-(1R)-menthyl ether is reported. Conditions for the deprotection of (1R)-menthoxymethyl ethers are described which do not lead to racemisation of homochiral alcohols. The usefulness of the (1R)-menthoxymethyl ether group (MM) as a simple means of measuring enantiomeric excess in a reaction sequence starting from ethyl lactate is outlined.

引用

页码：833 / 836

页数：4

共 10 条

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