ADDITION OF PERFLUOROALKYL IODIDES TO 4-PENTENOL AND ITS DERIVATIVES - ONE-POT PREPARATION OF 2-[(F-ALKYL)METHYL]-TETRAHYDROFURANS

被引：16

作者：

GREINER, J

MILIUS, A

RIESS, JG

机构：

[1] Laboratoire de Chimie Moléculaire, Unité de Recherche Associée au CNRS, Université de Nice-Sophia Antipolis, 06108 Nice Cédex 2, Parc Valrose

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1992年 / 56卷 / 03期

关键词：

D O I：

10.1016/S0022-1139(00)81175-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Depending on the nature of the alkaline medium, the radical addition of perfluoroalkyl iodides to 4-pentenol gives a mixture of 5-(F-alkyl)-4-pentenol and 2-[(F-alkyl)-methyl]tetrahydrofuran, or the latter alone.

引用

页码：285 / 293

页数：9

共 33 条

[1]

ABROSKINA TN, 1972, IAN SSSR KH, V74, P1823

[2]

AHLBRECHT AH, 1966, Patent No. 3285975

[3] ADDITION-REACTION OF 3,3,3-TRIFLUOROPROPENE TO TETRAHYDROFURAN - TELOMERIC GROWTH VIA FREE-RADICAL REARRANGEMENTS [J].

BERGSTROM, DE ;

NG, MW ;

WONG, JJ .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1983, (04) :741-745

[4] CLEAVAGE OF ETHERS [J].

BHATT, MV ;

KULKARNI, SU .

SYNTHESIS-STUTTGART, 1983, (04) :249-282

[5] QUANTITATIVE METHOD FOR THE SYNTHESIS OF PERFLUOROALKYL ETHANOL RFCH2CH2OH FROM 2-PERFLUOROALKYL-1-IODOETHANE RFCH2CH2I - (RF=CNF2N+1, N IS EVEN) [J].

BLANCOU, H ;

BENEFICE, S ;

COMMEYRAS, A .

JOURNAL OF FLUORINE CHEMISTRY, 1983, 23 (01) :57-65

[6] SOME APPROACHES TO THE SYNTHESIS OF FLUORINATED ALCOHOLS AND ESTERS .2. USE OF F-ALKYL IODIDES FOR THE SYNTHESIS OF F-ALKYL ALKANOLS [J].

BRACE, NO .

JOURNAL OF FLUORINE CHEMISTRY, 1982, 20 (03) :313-327

[7] I-IODO-2-(PERFLUOROALKY)CYCLOALKANES BY FREE RADICAL SDDITION OF IODOPERFLUOROALKANES TO CYCLOHEXANE AND CYCLOPENTENE [J].

BRACE, NO .

JOURNAL OF ORGANIC CHEMISTRY, 1963, 28 (11) :3093-&

[8]

Breitmaier E., 1974, 13C NMR SPECTROSCOPY

[9]

BURTON DJ, 1966, TETRAHEDRON LETT, P5163

[10] ELECTROLYTIC REDUCTIVE COUPLING - ADDITION OF PERFLUOROALKYLIODIDES TO ALCENES [J].

CALAS, P ;

COMMEYRAS, A .

JOURNAL OF FLUORINE CHEMISTRY, 1980, 16 (06) :553-554

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