SYNTHESIS OF POLYVINYLAMINE AND POLYMER ANALOGOUS REACTIONS

被引：6

作者：

FISCHER, T ^{[1
]}

HEITZ, W ^{[1
]}

机构：

[1] PHILIPPS UNIV MARBURG,FB PHYS CHEM 14,INST POLYMERE & WISSENSCH ZENTRUM MAT WISSENSCH,D-35032 MARBURG,GERMANY

来源：

MACROMOLECULAR CHEMISTRY AND PHYSICS | 1994年 / 195卷 / 02期

关键词：

D O I：

10.1002/macp.1994.021950225

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Polyvinylamine (PVVAm) was synthesized using the precursor poly(tert-butyl N-vinylcarbamate) (PTBNVC). The monomer synthesis was improved, and the control of the molecular weight of the PTBNVC and the PVAm by a transfer reaction with the solvent is demonstrated. TBNVC was radically polymerized. In suspension polymerization molecular weights of 10(6) g/mol are accessible. Different polymer analogous reactions were carried out. The resulting polymers are methylated polyvinylamine, poly(N-vinylureas), poly(N-vinylalkanamides) and PVAm-adducts with acrylic acid derivatives.

引用

页码：679 / 687

页数：9

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