ENZYMATIC PREPARATION OF ENANTIOMERICALLY PURE (1R,2R)-2-AMINOCYCLOHEXANOLS AND (1S,2S)-2-AMINOCYCLOHEXANOLS

被引：12

作者：

TAKADA, H

TAKAGI, S

KAWAKUBO, H

机构：

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1994年 / 67卷 / 04期

关键词：

D O I：

10.1246/bcsj.67.1196

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The Pseudomonas cepacia lipase-catalyzed enantioselective hydrolysis of trans-2-(t-butoxycarbonyl)aminocyclohexyl acetate was readily accomplished to provide a practical method for the industrial preparation of enantiomerically pure (1R,2R)- and (1S,2S)-2-aminocyclohexanols.

引用

页码：1196 / 1197

页数：2

共 7 条

[1] ASYMMETRIC RING-OPENING OF CYCLOHEXENE OXIDE WITH TRIMETHYLSILYL AZIDE IN THE PRESENCE OF TITANIUM ISOPROPOXIDE CHIRAL LIGAND
EMZIANE, M
SUTOWARDOYO, KI
SINOU, D
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1988, 346 (01) : C7 - C10
[2] A NOVEL AND EFFICIENT SYNTHESIS OF (+)- AND (-)-TRANS-2-AMINOCYCLOHEXANOL BY ENZYMATIC-HYDROLYSIS
FABER, K
HONIG, H
SEUFERWASSERTHAL, P
[J]. TETRAHEDRON LETTERS, 1988, 29 (16) : 1903 - 1904
[3] HONIG H, 1990, SYNTHESIS-STUTTGART, P1137
[4] KINETIC RESOLUTION OF RACEMIC BETA-HYDROXY AMINES BY ENANTIOSELECTIVE N-OXIDE FORMATION
MIYANO, S
LU, LDL
VITI, SM
SHARPLESS, KB
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1985, 50 (22) : 4350 - 4360
[5] A CONVENIENT METHOD FOR OBTAINING TRANS-2-AMINOCYCLOHEXANOL AND TRANS-2-AMINOCYCLOPENTANOL IN ENANTIOMERICALLY PURE FORM
OVERMAN, LE
SUGAI, S
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1985, 50 (21) : 4154 - 4155
[6] STUDIES ON ANTIBIOTICS AND RELATED SUBSTANCES .17. SYNTHESES OF TRANS-2-AMINOCYCLOHEXYL-D-GLUCOSAMINIDES
SUAMI, T
OGAWA, S
UMEZAWA, S
[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1963, 36 (04) : 459 - 462
[7] A NEW SYNTHESIS OF OPTICALLY-ACTIVE TRANS BETA-AMINO ALCOHOLS BY ASYMMETRIC RING-OPENING OF SYMMETRICAL OXIRANES
YAMASHITA, H
[J]. CHEMISTRY LETTERS, 1987, (03) : 525 - 528

← 1 →