SYNTHESIS AND STRUCTURES OF N-ALKYLATED AZATITANATRANES

被引：35

作者：

SCHUBART, M

ODWYER, L

GADE, LH

LI, WS

MCPARTLIN, M

机构：

[1] UNIV WURZBURG,INST ANORGAN CHEM,AM HUBLAND,D-97074 WURZBURG,GERMANY

[2] UNIV N LONDON,SCH CHEM,LONDON N7 8DB,ENGLAND

来源：

INORGANIC CHEMISTRY | 1994年 / 33卷 / 18期

关键词：

D O I：

10.1021/ic00096a012

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The N-alkylated azatitanatranes N(CH2CH2NR)3TiCl [R = Me (1), Et (2), i-Pr (3)] have been prepared and 1 and 3 structurally characterized by X-ray crystallography: 1, orthorhombic, Pmna, a = 11.293(3) angstrom, b = 11.977(3) angstrom, c = 9.722(3) angstrom, V = 1314.96 angstrom3, Z = 4, R = 0.0629; 3, cubic, Pa3, a = 15.928(4) angstrom, V = 4040.95 angstrom3, Z = 8, R = 0.0792. The halide ligand in 2 and 3 could be replaced by more labile ligands by chloride abstraction using the appropriate silver salts. A single-crystal X-ray structure analysis of N(CH2CH2NEt)3TiOSO2CF3 (4), the first azatrane-triflate to be reported, was carried out. Crystal data for 4: triclinic, P1BAR (No. 2), a = 16.039(4) angstrom, b = 16.473(4) angstrom, c = 8.954(3) angstrom, alpha = 105.75-degrees, beta = 106.17(2)-degrees, gamma = 107.54(2)-degrees, V = 1996.33 angstrom3, Z = 4, R = 0.0842. The titanium amido complexes reported here may find use as building blocks in more complex structural arrays.

引用

页码：3893 / 3898

页数：6

共 34 条

[1] PREPARATION, PROPERTIES, AND CRYSTAL-STRUCTURES OF THE MONOCHLOROTRIS-[BIS(TRIMETHYLSILYL)AMIDO]-COMPOUNDS OF TITANIUM, ZIRCONIUM, AND HAFNIUM
AIROLDI, C
BRADLEY, DC
CHUDZYNSKA, H
HURSTHOUSE, MB
ABDULMALIK, KM
RAITHBY, PR
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1980, (10): : 2010 - 2015
[2] SPIROCYCLIC TITANIUM AMIDES CONTAINING THE DIPHENYLSILA-TITANA-DIAZACYCLOBUTANE FRAGMENT - CRYSTAL AND MOLECULAR-STRUCTURE OF TI[(NSIME3)2SIPH2]2
BEIERSDORF, WD
BRAUER, DJ
BURGER, H
[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1981, 475 (04): : 56 - 66
[3] SYNTHESIS AND STRUCTURE OF CP2TI(SO3CF3)(THF)
BERHALTER, K
THEWALT, U
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 420 (01) : 53 - 56
[4] SYNTHESIS, PHOTOCHEMISTRY AND X-RAY CRYSTAL-STRUCTURES OF THE METHYLTRIS[BIS(TRIMETHYLSILYL)AMIDO] COMPOUNDS METI[N(SIME3)2]3 AND MEZR[N(SIME3)2]3
BRADLEY, DC
CHUDZYNSKA, H
BACKERDIRKS, JDJ
HURSTHOUSE, MB
IBRAHIM, AA
MOTEVALLI, M
SULLIVAN, AC
[J]. POLYHEDRON, 1990, 9 (11) : 1423 - 1427
[5] TITANIUM NITROGEN-COMPOUNDS .29. CRYSTAL AND MOLECULAR-STRUCTURE OF SPIROCYCLIC AMIDES OF TITANIUM AND ZIRCONIUM WITH THE LIGAND ME2SI(N-T-BUTYL)2
BRAUER, DJ
BURGER, H
ESSIG, E
GESCHWANDTNER, W
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1980, 190 (04) : 343 - 351
[6] TITANIUM-NITROGEN COMPLEXES .27. BENZYLTITANO-DERIVATIVES OF CYCLIC SILYLAMIDE - CRYSTAL AND MOLECULAR-STRUCTURE OF (BENZYL)2TI[N(SIME2NME)2SIME2]2
BRAUER, DJ
BURGER, H
WIEGEL, K
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1978, 150 (02) : 215 - 231
[7] TITANIUM NITROGEN-COMPOUNDS .19. SYNTHESIS AND STRUCTURE OF SPIROCYCLIC TITANIUM SILYLAMIDE
BURGER, H
WIEGEL, K
THEWALT, U
SCHOMBURG, D
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1975, 87 (03) : 301 - 309
[8] METALATION OF THE ISOPROPENYL GROUP BY PLATINUM(II) - MECHANISM OF FORMATION OF ISOMERIC SIGMA-ALLYLIC AND SIGMA-VINYLIC 6-MEMBERED CHELATE RINGS - X-RAY STRUCTURE OF THE SIGMA-VINYLIC COMPLEX DI-MU-ACETATO-BIS-([2-(ORTHO-DIPHENYLARSINOPHENYL)PROPENYL-C'AS]PLATINUM(II))
COOPER, MK
GUERNEY, PJ
GOODWIN, HJ
MCPARTLIN, M
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1982, (04): : 757 - 764
[9] CRISTOU V, 1993, ANGEW CHEM INT EDIT, V32, P1450
[10] PHOSPHINIDENETANTALUM(V) COMPLEXES OF THE TYPE [(N3N)TA=PR] AS PHOSPHA-WITTIG REAGENTS (R = PH, CY, TBU, N3N = (ME3SINCCH2CH2)3N)
CUMMINS, CC
SCHROCK, RR
DAVIS, WM
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1993, 32 (05): : 756 - 759

← 1 2 3 4 →