HEAT OF DIMERIZATION OF SOME CARBOXYLIC ACIDS IN VAPOUR PHASE DETERMINED BY A SPECTROSCOPIC METHOD

被引:103
作者
CLAGUE, ADH
BERNSTEI.HJ
机构
[1] Division of Pure Chemistry, National Research Council of Canada, Ottawa
来源
SPECTROCHIMICA ACTA PART A-MOLECULAR SPECTROSCOPY | 1969年 / A 25卷 / 03期
关键词
D O I
10.1016/0584-8539(69)80009-7
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
In this work, the lower molecular weight carboxylic acids, formic, acetic, propionic, n-butyric, isobutric and trimethylacetic have been studied to find, firstly, whether there is any trend in thermodynamic properties due to mass or structure of the alkyl substituent, and secondly, to demonstrate the utility and limitations of a simple spectroscopic procedure for the determination of thermodynamic properties. © 1969.
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页码:593 / &
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