PARTIAL MOLAL VOLUMES OF ORGANIC-COMPOUNDS IN CARBON-TETRACHLORIDE .3. AROMATIC-HYDROCARBONS - STERIC EFFECTS

被引：29

作者：

SHAHIDI, F

FARRELL, PG

EDWARD, JT

CANONNE, P

机构：

[1] MCGILL UNIV,DEPT CHEM,MONTREAL H3A 2K6,QUEBEC,CANADA

[2] UNIV LAVAL,DEPT CHEM,QUEBEC CITY 10,QUEBEC,CANADA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1979年 / 44卷 / 06期

关键词：

D O I：

10.1021/jo01320a012

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The partial molal volumes of 31 aromatic and alkylaromatic hydrocarbons in carbon tetrachloride solution at 25 °C may be calculated with reasonable accuracy by addition of group increments (═C<, 3.03; ═CH-, 13.22 mL mol-1; established values for methyl, methylene, and methine) to a covolume of 11.61 mL mol-1 and subtraction of fixed amounts for structural features known to involve intramolecular overcrowding. © 1979, American Chemical Society. All rights reserved.

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页码：950 / 953

页数：4

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