AN EXTREMELY EFFICIENT SYNTHESIS OF THIOPHENE 1,1-DIOXIDES - OXIDATION OF THIOPHENE DERIVATIVES WITH DIMETHYLDIOXIRANE

被引：41

作者：

MIYAHARA, Y

INAZU, T

机构：

[1] Department of Chemistry, Faculty of Science, Kyushu University 33 Hakozaki, Higashi-ku, Fukuoka

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 41期

关键词：

D O I：

10.1016/S0040-4039(00)98003-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Dimethyldioxirane was found to oxidize electron-rich thiophene derivatives, including sterically hindered thiophenophanes, to the corresponding thiophene 1,1-dioxides in excellent yields. Electronwithdrawing groups on a thiophene ring substantially retarded the oxidation, but dimethyldioxitane remained superior to other reagents. © 1990.

引用

页码：5955 / 5958

页数：4

共 32 条

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