TOTAL SYNTHESIS OF DL-STENINE

被引:69
作者
CHEN, CY [1 ]
HART, DJ [1 ]
机构
[1] OHIO STATE UNIV,DEPT CHEM,120 W 18TH AVE,COLUMBUS,OH 43210
关键词
D O I
10.1021/jo00313a003
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Intramolecular Diels-Alder cycloadduct 10 was converted to the Stemona alkaloid stenine (1) via a reaction sequence that features a Curtius rearrangement (12 --> 13), Eschenmoser-Claisen rearrangement (19 --> 20) and stereoselective free radical allylation (4 --> 21).
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页码:6236 / 6240
页数:5
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