FORMATION OF NOVEL DELOCALIZED DIPHOSPHAZENE UPON COMPLEXATION - THE PREPARATION AND X-RAY STRUCTURE OF OS3(CO)10[(CF3)2P=N=PPH3]2

被引：3

作者：

ANG, HG ^{[1
]}

CAI, YM ^{[1
]}

KWIK, WL ^{[1
]}

MORRISON, EC ^{[1
]}

TOCHER, DA ^{[1
]}

机构：

[1] UNIV LONDON UNIV COLL,DEPT CHEM,LONDON WC1H 0AJ,ENGLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 403卷 / 03期

关键词：

D O I：

10.1016/0022-328X(91)86486-A

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The compound Os3(CO)10[(CF3)2P = N = PPh3]2 obtained from the reaction of Os3(CO)10(CH3CN)2 with (CF3)2P-N = PPh3, has been characterized by X-ray crystallography. The osmium atoms form an approximate isoceles triangle. Both diphosphazene ligands which assume equatorial sites, contain unusually short P-N bonds, from P-N = P to P = N = P upon coordination to osmium metals.

引用

页码：383 / 385

页数：3

共 15 条

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