INFLUENCE OF LARGE MAGNETIC-FIELDS ON THE DYNAMIC BEHAVIOR OF A RADICAL PAIR PRODUCED BY PHOTOREDUCTION OF BENZOPHENONE IN A MICELLAR SOLUTION

被引:28
作者
SAKAGUCHI, Y
HAYASHI, H
机构
关键词
D O I
10.1246/cl.1993.1183
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The photochemical reaction of benzophenone in a micellar sodium dodecylsulfate solution was investigated under magnetic fields of 0-10 T. The decrease of decay rate of the ketyl radical and the increase of the yield of the escaped radical were saturated around 2 T. The contribution of the DELTAg mechanism was not observed below 10 T since the DELTAg value is very small for this system.
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页码:1183 / 1186
页数:4
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