INDUCTIVE EFFECTS ON BRIDGING GA-CL DISTANCES - THE MOLECULAR-STRUCTURE OF THE DICHLORO(METHYL) GALLIUM DIMER, [ME2CL2GA2(MU-CL)2], DETERMINED BY GAS ELECTRON-DIFFRACTION

被引：9

作者：

AKOBIYA, MM

BREGADZE, VI

GOLUBINSKAYA, LM

GUNDERSEN, S

HAALAND, A

VOLDEN, HV

MASTRYUKOV, VS

SHISHKOV, IF

机构：

[1] UNIV OSLO,DEPT CHEM,BOX 1033 BLINDERN,N-0315 OSLO 3,NORWAY

[2] AN NESMEYANOV ORGANOELEMENT CPDS INEOS INST,MOSCOW 117813,RUSSIA

[3] UNIV MOSCOW,DEPT CHEM,MOSCOW 117234,RUSSIA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 467卷 / 02期

关键词：

GALLIUM; CHLORINE; ELECTRON DIFFRACTION;

D O I：

10.1016/0022-328X(94)80001-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The gas-phase electron diffraction data for [Me2Cl2Ga2(mu-Cl)2] are consistent with a trans model of C2h symmetry and bond distances (r(a)) Ga-C = 194.9(7) pm, Ga-Cl(ta) = 212.9(3) pm and Ga-Cl(b) = 233.9(3) pm.

引用

页码：161 / 163

页数：3

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