ELECTRONIC-PROPERTIES OF ALKALI-METAL-HYDROGEN-GRAPHITE INTERCALATION COMPOUNDS

被引：2

作者：

ENOKI, T ^{[1
]}

SHINDO, K ^{[1
]}

SAKAMOTO, N ^{[1
]}

NAKAZAWA, K ^{[1
]}

SUZUKI, K ^{[1
]}

SUGIHARA, K ^{[1
]}

机构：

[1] NIHON UNIV,COLL PHARM,FUNABASHI,CHIBA 274,JAPAN

来源：

ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS | 1993年 / 181卷

关键词：

ALKALI METAL-HYDROGEN-GRAPHITE; INTERCALATION COMPOUNDS; ELECTRICAL CONDUCTIVITY; THERMOELECTRIC POWER;

D O I：

10.1524/zpch.1993.181.Part_1_2.075

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Alkali-metal-hydrogen-graphite intercalation compounds (GIC) are classified to be a metal-hydrogen system. Electronic properties have been investigated by means of conductivities and thermoelectric powers for isostructural sodium-hydride (NaH) and potassium-mercury (KHg)-GICs having alkali-metal-hydrogen/mercury-alkali-metal sandwiched triple atomic layers in graphitic galleries, in comparison with an isostructural KH-GIC. From the experimental results, it is suggested that carrier concentrations in intercalate layers decrease in the order of KHg-GIC > KH-GIC > NaH-GIC, so that the electronic structure of hydrogen/mercury varies from delocalized to localized one in the same order.

引用

页码：75 / 82

页数：8

共 11 条

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