REACTIONS OF NH WITH C2H6 AND C3H8 IN THE LIQUID-PHASE

被引：17

作者：

TSUNASHIMA, S

HOTTA, M

SATO, S

机构：

[1] Department of Applied Physics, Tokyo Institute of Technology, 152, Ookayama, Meguro-ku, Tokyo, Japan

来源：

CHEMICAL PHYSICS LETTERS | 1979年 / 64卷 / 03期

关键词：

D O I：

10.1016/0009-2614(79)80216-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

HN3 was photolyzed in C2H6 or C3H8 solution at the temperature of dry ice-methanol. The main products were N2 and C2H5NH2 or n-C3H7NH2 and i-C3H7NH2. NH3 and H2 were also formed as minor products. Possible reaction mechanisms are discussed. It is suggested that alkylamine is mainly formed by the insertion of NH(a1Δ) into the CH bonds of C2H6 or C3H8. © 1979.

引用

页码：435 / 439

页数：5

共 29 条

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