RESONANT PHOTOEMISSION AT THE 3P-CORE THRESHOLD FROM QUASI-ATOMIC NI IN NICKEL-PHTHALOCYANINE

被引:27
作者
IWAN, M [1 ]
KOCH, EE [1 ]
机构
[1] DESY,SYNCHROTRONSTRAHLUNGSLAB,D-2000 HAMBURG 52,FED REP GER
关键词
D O I
10.1016/0038-1098(79)90608-2
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
In nickel-phthalocyanine a resonant enhancement at the 3p-Ni photo-absorption maximum (hv {reversed tilde equals} 68.5 eV) of a peak approximately 6 eV below the maximum of the Ni 3d derived states is observed in photoemission experiments with variable excitation energy (synchrotron radiation). Our observation of this resonance, explained by configuration interaction of Ni 3p→3d and 3d-continuum transitions, gives direct evidence for the atomic nature of the 6 eV resonance structure in photoemission from bulk Ni. © 1979.
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页码:261 / 264
页数:4
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