ROLE OF ENTROPY IN FORMATION OF VANDERWAALS COMPLEXES

被引：11

作者：

HOBZA, P ^{[1
]}

CARSKY, P ^{[1
]}

ZAHRADNIK, R ^{[1
]}

机构：

[1] CZECHOSLOVAK ACAD SCI, J HEYROVSKY INST PHYS CHEM & ELECTROCHEM, CS-12138 PRAGUE 2, CZECHOSLOVAKIA

来源：

INTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY | 1979年 / 16卷 / 02期

关键词：

D O I：

10.1002/qua.560160206

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The TΔS0 term has been estimated for various types of van der Waals molecules and its importance for the stability predictions has been demonstrated. With hydrogen‐bonded complexes the absolute values of ΔH0 and TΔS0 are comparable at 289°K. With true van der Waals molecules the TΔS0 term even represents a dominant contribution to ΔG0. Copyright © 1979 John Wiley & Sons, Inc.

引用

页码：257 / 260

页数：4

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