POLY[3-(4-OCTYLPHENYL)THIOPHENE], A NEW PROCESSIBLE CONDUCTING POLYMER

被引：59

作者：

PEI, Q ^{[1
]}

JARVINEN, H ^{[1
]}

OSTERHOLM, JE ^{[1
]}

INGANAS, O ^{[1
]}

LAAKSO, J ^{[1
]}

机构：

[1] NESTE OY RES CTR,SF-06850 KULJU,FINLAND

来源：

MACROMOLECULES | 1992年 / 25卷 / 17期

关键词：

D O I：

10.1021/ma00043a009

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A new, processible conducting polymer, poly[3-(4-octylphenyl)thiophene] has been chemically synthesized in chloroform using FeCl3 as the oxidant/reagent. The polymer, which is soluble in organic solvents such as chloroform, has been characterized using optical, electrical, and electrochemical methods. We observed a suppressed thermochromism and thermal undoping in this polymer compared to the case of poly(3-alkylthiophene) due to the separation effect of the benzene rings between the poly(thiophene) main chain and the flexible alkyl side chains. At low doping levels, polarons are found to be the charge carriers.

引用

页码：4297 / 4301

页数：5

共 21 条

[1] POLARONS, BIPOLARONS, AND SOLITONS IN CONDUCTING POLYMERS
BREDAS, JL
STREET, GB
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1985, 18 (10) : 309 - 315
[2] GENERATION OF STABILIZED POLARONS AND BIPOLARONS ON EXTENDED MODEL THIOPHENE OLIGOMERS
FICHOU, D
XU, B
HOROWITZ, G
GARNIER, F
[J]. SYNTHETIC METALS, 1991, 41 (1-2) : 463 - 469
[3] GRANSTROM M, IN PRESS SYNTH MET
[4] THERMAL UNDOPING IN POLY(3-ALKYLTHIOPHENES)
GUSTAFSSON, G
INGANAS, O
NILSSON, JO
LIEDBERG, B
[J]. SYNTHETIC METALS, 1988, 26 (03) : 297 - 309
[5] GUSTAFSSON G, 1989, SYNTHETIC MET, V28, pC427, DOI 10.1016/0379-6779(89)90555-9
[6] HOEVE WH, 1991, J AM CHEM SOC, V113, P5887
[7] THERMOCHROMIC AND SOLVATOCHROMIC EFFECTS IN POLY(3-HEXYLTHIOPHENE)
INGANAS, O
SALANECK, WR
OSTERHOLM, JE
LAAKSO, J
[J]. SYNTHETIC METALS, 1988, 22 (04) : 395 - 406
[8] HIGHLY CONDUCTING, SOLUBLE, AND ENVIRONMENTALLY-STABLE POLY(3-ALKYLTHIOPHENES)
JEN, KY
MILLER, GG
ELSENBAUMER, RL
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (17) : 1346 - 1347
[9] OSTERHOLM JE, 1989, SYNTHETIC MET, V28, P435
[10] POLY(3-OCTYLTHIOPHENE-CO-3-METHYLTHIOPHENE), A PROCESSIBLE AND STABLE CONDUCTING COPOLYMER
PEI, QB
INGANAS, O
[J]. SYNTHETIC METALS, 1992, 46 (03) : 353 - 357

← 1 2 3 →