ELECTROCHEMICAL QUARTZ-CRYSTAL MICROBALANCE STUDY ON ELECTROPOLYMERIZATION OF M-PHENYLENEDIAMINE - EFFECTS OF ANILINE AND POLYANILINE

被引：30

作者：

SI, SH ^{[1
]}

XU, YJ ^{[1
]}

NIE, LH ^{[1
]}

YAO, SZ ^{[1
]}

机构：

[1] HUNAN UNIV,MEW MAT RES INST,CHANGSHA 410082,PEOPLES R CHINA

来源：

ELECTROCHIMICA ACTA | 1995年 / 40卷 / 17期

基金：

美国国家科学基金会;

关键词：

ELECTROPOLYMERIZATION; M-PHENYLENEDIAMINE; POLYANILINE; SURFACE MODIFICATION; IMMOBILIZATION; QCM;

D O I：

10.1016/0013-4686(95)00272-G

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Electrochemical oxidative polymerization of m-phenylenediamine (mPD) gave a nonconducting limited-thickness polymer film on the gold electrode. To obtain new functional films for surface modification, the electrochemical copolymerization of aniline (An) and mPD at different ratios of the monomers was performed by potential scanning between -0.1 V and 0.92 V (vs. see). With quartz crystal microbalance measurements, the growth rate of the film and the amount of protein cross-linked on the polymer film were investigated. The results showed that a - NH2 functionalized film could be obtained by the copolymerization of An with mPD at appropriate monomer ratio, and that the precoated poly-An film enhanced not only the depositing rate of poly-mPD but also the immobilizing capacity of the poly-mPD film remarkably.

引用

页码：2715 / 2721

页数：7

共 21 条

[1]

BARTLETT PN, 1991, J ELECTROANAL CHEM, V261, P1

[2]

BERGERON JY, 1991, POLYM COMMUN, V32, P403

[3] MEASUREMENT OF INTERFACIAL PROCESSES AT ELECTRODE SURFACES WITH THE ELECTROCHEMICAL QUARTZ CRYSTAL MICROBALANCE [J].

BUTTRY, DA ;

WARD, MD .

CHEMICAL REVIEWS, 1992, 92 (06) :1355-1379

[4] ELECTROSYNTHESIS AND PROPERTIES OF RING-SUBSTITUTED POLYANILINES [J].

CATTARIN, S ;

DOUBOVA, L ;

MENGOLI, G ;

ZOTTI, G .

ELECTROCHIMICA ACTA, 1988, 33 (08) :1077-1084

[5] ELECTROACTIVE POLYANILINE FILMS [J].

DIAZ, AF ;

LOGAN, JA .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1980, 111 (01) :111-114

[6] POLYANILINE, A NOVEL CONDUCTING POLYMER - MORPHOLOGY AND CHEMISTRY OF ITS OXIDATION AND REDUCTION IN AQUEOUS-ELECTROLYTES [J].

HUANG, WS ;

HUMPHREY, BD ;

MACDIARMID, AG .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1986, 82 :2385-&

[7] ELECTROCHEMICAL REACTIONS CONCERNED WITH ELECTROCHROMISM OF POLYANILINE FILM-COATED ELECTRODES [J].

KOBAYASHI, T ;

YONEYAMA, H ;

TAMURA, H .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1984, 177 (1-2) :281-291

[8] LONG-TERM STABILITY AND IMPROVED REUSABILITY OF A PIEZOELECTRIC IMMUNOSENSOR FOR HUMAN ERYTHROCYTES [J].

KONIG, B ;

GRATZEL, M .

ANALYTICA CHIMICA ACTA, 1993, 280 (01) :37-41

[9] CHARACTERIZATION OF ELECTRODEPOSITED COPOLYMERS OF ANILINE AND METANILIC ACID [J].

LEE, JY ;

SU, XH ;

CUI, CQ .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1994, 367 (1-2) :71-78

[10] DETERMINATION OF ION POPULATIONS AND SOLVENT CONTENT AS FUNCTIONS OF REDOX STATE AND PH IN POLYANILINE [J].

ORATA, D ;

BUTTRY, DA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (12) :3574-3581

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