OXIDATION OF FREE-ELECTRON METALS - MULTIPLET SPLITTING

被引：41

作者：

WIJERS, C ^{[1
]}

ADRIAENS, MR ^{[1
]}

FEUERBACHER, B ^{[1
]}

机构：

[1] EUROPEAN SPACE RES ORG,DEPT SPACE SCI,NOORDWIJK,NETHERLANDS

来源：

SURFACE SCIENCE | 1979年 / 80卷 / 01期

关键词：

D O I：

10.1016/0039-6028(79)90692-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Ultraviolet photoemission spectra are presented on the early stages of oxidation of Cs, Rb, and K. Two distinctly different phases of oxidation can be identified, which are interpreted as atomic oxygen incorporated into the top metal layer, followed by the formation of a metal-oxygen surface molecular compound. The sharp, multiple adsorbate-induced structures observed indicate local interaction with atomic-like multiplet splitting. © 1979.

引用

页码：317 / 324

页数：8

共 24 条

[1] ELECTRONIC-STRUCTURE OF OXYGEN OVERLAYER ON AL(100)
BATRA, IP
CIRACI, S
[J]. PHYSICAL REVIEW LETTERS, 1977, 39 (12) : 774 - 777
[2] PHOTOELECTRON-SPECTROSCOPY OF ALKALI-METALS RB AND CS AND THEIR METAL RICH OXIDES
EBBINGHAUS, G
BRAUN, W
SIMON, A
[J]. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1976, 31 (09): : 1219 - 1223
[3] PHOTOEMISSION FROM METALLIC CESIUM OXIDE-FILMS
EBBINGHAUS, G
BRAUN, W
SIMON, A
BERRESHEIM, K
[J]. PHYSICAL REVIEW LETTERS, 1976, 37 (26) : 1770 - 1773
[4] Edqvist O., 1970, Physica Scripta, V1, P25, DOI 10.1088/0031-8949/1/1/004
[5] ADSORPTION OF OXYGEN ON SILVER SINGLE-CRYSTAL SURFACES
ENGELHARDT, HA
MENZEL, D
[J]. SURFACE SCIENCE, 1976, 57 (02) : 591 - 618
[6] FEUERBACHER B, 1977, 7TH P INT VAC C VIEN, P1149
[7] CHEMISORPTION OF O AND H ON FREE-ELECTRON-LIKE METALS AL AND MG STUDIED BY PHOTOELECTRON-SPECTROSCOPY
FLODSTROM, SA
PETERSSON, LG
HAGSTROM, SBM
[J]. JOURNAL OF VACUUM SCIENCE & TECHNOLOGY, 1976, 13 (01): : 280 - 282
[8] PHOTOEMISSION STUDY OF CLEAN AND OXYGEN-COVERED ALUMINUM AND MAGNESIUM
FLODSTROM, SA
PETERSSON, LG
HAGSTROM, SBM
[J]. SOLID STATE COMMUNICATIONS, 1976, 19 (03) : 257 - 260
[9] XPS, UPS AND XAES STUDIES OF OXYGEN-ADSORPTION ON POLYCRYSTALLINE MGAT-100 AND -300K
FUGGLE, JC
[J]. SURFACE SCIENCE, 1977, 69 (02) : 581 - 608
[10] OXIDATION OF CS-UV PHOTOEMISSION STUDIES
GREGORY, PE
CHYE, P
SUNAMI, H
SPICER, WE
[J]. JOURNAL OF APPLIED PHYSICS, 1975, 46 (08) : 3525 - 3529

← 1 2 3 →