PENTACOORDINATE SILICON-COMPOUNDS - REACTIONS OF SILATRANES WITH NUCLEOPHILES

被引：25

作者：

CERVEAU, G ^{[1
]}

CHUIT, C ^{[1
]}

CORRIU, RJP ^{[1
]}

NAYYAR, NK ^{[1
]}

REYE, C ^{[1
]}

机构：

[1] UNIV MONTPELLIER 2,HETEROCHIM & AMINO ACIDES LAB,CNRS,URA 1097,PL EUGENE BATAILLON,F-34095 MONTPELLIER 2,FRANCE

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 389卷 / 02期

关键词：

D O I：

10.1016/0022-328X(90)85408-Q

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of hydro, organyl and halosilatranes with nucleophiles have been studied. Substitution involving cleavage of equatorial SiO bonds is always observed. Silatranes exhibit reactivity quite different from that of analogous trialkoxysilanes or anionic pentacoordinate silicon compounds. © 1990.

引用

页码：159 / 168

页数：10

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