VIBRONIC EFFECTS IN THE PREDISSOCIATION OF THE C-1-PI-U STATE OF C2N2

被引:12
作者
MILLER, GE [1 ]
JACKSON, WM [1 ]
HALPERN, JB [1 ]
机构
[1] HOWARD UNIV,DEPT CHEM,WASHINGTON,DC 20059
关键词
D O I
10.1063/1.438217
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The partitioning of excess photochemical energy as a function of the vibrational energy of the C 1IIu state of C 2N2 has been measured. Surprisal theory has been used to analyze the data and it shows that complete randomization does not occur before dissociation. The results are also inconsistent with the predictions of the quasidiatomic theory for photodissociation. © 1979 American Institute of Physics.
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页码:4625 / 4630
页数:6
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