NEW METHOD OF ZINC ACTIVATION BY ELECTROCHEMISTRY - SYNTHETIC APPLICATIONS TO THE BLAISE REACTION

被引：13

作者：

ZYLBER, N ^{[1
]}

ZYLBER, J ^{[1
]}

ROLLIN, Y ^{[1
]}

DUNACH, E ^{[1
]}

PERICHON, J ^{[1
]}

机构：

[1] LAB ELECTROCHIM CATALYSE & SYNTHESE ORGAN,CNRS,UMR 28,2 RUE HENRI DUNANT,F-94320 THIAIS,FRANCE

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 444卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(93)83045-W

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new electrochemical zinc metal activation method based on the cathodic reduction of a catalytic amount of zinc bromide in the presence of a zinc anode is described. This procedure is applied to the coupling of alpha-bromoesters with nitriles, and affords beta-ketoesters in good yield.

引用

页码：1 / 4

页数：4

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