DIENES AS CHIRAL TEMPLATES - EASY ACCESS TO PURE (2S,3S,4R)-4-HYDROXY-2,3-EPOXYCYCLOHEX-5-EN-1-ONE

被引：8

作者：

MAUVAIS, A ^{[1
]}

WINTERFELDT, E ^{[1
]}

机构：

[1] UNIV HANNOVER,INST ORGAN CHEM,SCHNEIDERBERG 1B,W-3000 HANNOVER 1,GERMANY

来源：

TETRAHEDRON | 1993年 / 49卷 / 26期

关键词：

CHIRAL DIENE; CHIRAL TEMPLATE; RETRO-DIELS-ALDER REACTION; FLASH VACUUM THERMOLYSIS; FAVORSKII REARRANGEMENT;

D O I：

10.1016/S0040-4020(01)87948-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The title compound 6 was obtained stereospecifically through a concise sequence including a Diels-Alder reaction with the chiral diene 2 and the retro reaction. The Favorskii rearrangement starting from the intermediate epoxide 4 was found to be regioselective.

引用

页码：5817 / 5822

页数：6

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