PREPARATION OF SODIUM IONIC CONDUCTOR BASED ON SOL-GEL METHOD USING AQUEOUS-SOLUTION

被引：12

作者：

SHIMIZU, Y

MICHISHITA, S

MURATA, T

机构：

[1] Department of Chemistry, Kyushu Institute of Technology, Tobata, Kitakyushu

来源：

JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS | 1995年 / 34卷 / 7A期

关键词：

SOL-GEL METHOD; NASICON; AQUEOUS SOLUTION; THICKFILM; NA+ CONDUCTOR;

D O I：

10.1143/JJAP.34.L833

中图分类号：

O59 [应用物理学];

学科分类号：

摘要：

A well-crystallized sodium super ionic conductor (NASICON: Na1+xZr2SixP3-xO12, 0 less than or equal to x less than or equal to 3) was synthesized by a sol-gel method from aqueous solutions of inorganic materials with an Na excess stoichiometric composition at a relatively low temperature of 850 degrees C. A trace of monoclinic ZrO2 was observed, however, with increasing calcination temperatures up to 1000 degrees C. It was found that the process of making sol from solutions was the most important step to reduce secondary phases such as ZrO2. NASICON thickfilms were also fabricated on a quartz substrate by a spin-coating method using a paste made from fine xerogel powder and isoamyl alcohol.

引用

收藏

页码：L833 / L836

页数：4

相关论文

共 12 条

[1] PHASE-TRANSFORMATION IN NA1+XSIXZR2P3-XO12 COMPOUNDS [J].

BOILOT, JP ;

SALANIE, JP ;

DESPLANCHES, G ;

LEPOTIER, D .

MATERIALS RESEARCH BULLETIN, 1979, 14 (11) :1469-1477

[2] PHYSICOCHEMICAL CHARACTERIZATION OF NA3ZR2SI2PO12 FINE POWDERS PREPARED BY SOL-GEL METHOD USING CITRATES [J].

CHOY, JH ;

HAN, YS ;

KIM, YH ;

SUH, KS .

JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 1993, 32 (3A) :1154-1159

[3] THE USE OF HYDROTHERMAL PROCEDURES TO SYNTHESIZE NASICON AND SOME COMMENTS ON THE STOICHIOMETRY OF NASICON PHASES [J].

CLEARFIELD, A ;

SUBRAMANIAN, MA ;

WANG, W ;

JERUS, P .

SOLID STATE IONICS, 1983, 9-10 (DEC) :895-902

[4] ORIENTATIONAL DISORDER, GLASS CRYSTAL TRANSITION AND SUPERIONIC CONDUCTIVITY IN NASICON [J].

COLOMBAN, P .

SOLID STATE IONICS, 1986, 21 (02) :97-115

[5] NASICON, AN IONIC CONDUCTOR FOR SOLID-STATE NA+-SELECTIVE ELECTRODE [J].

FABRY, P ;

GROS, JP ;

MILLIONBRODAZ, JF ;

KLEITZ, M .

SENSORS AND ACTUATORS, 1988, 15 (01) :33-49

[6] FAST NA+-ION TRANSPORT IN SKELETON STRUCTURES [J].

GOODENOUGH, JB ;

HONG, HYP ;

KAFALAS, JA .

MATERIALS RESEARCH BULLETIN, 1976, 11 (02) :203-220

[7] FABRICATION AND CHARACTERIZATION OF NASICON ELECTROLYTES [J].

GORDON, RS ;

MILLER, GR ;

MCENTIRE, BJ ;

BECK, ED ;

RASMUSSEN, JR .

SOLID STATE IONICS, 1981, 3-4 (AUG) :243-248

[8] NA-+ AND LI-+ NASICON SUPERIONIC CONDUCTORS THICK-FILMS [J].

PERTHUIS, H ;

VELASCO, G ;

COLOMBAN, P .

JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 1984, 23 (05) :534-543

[9] SYNTHESIS, CHARACTERIZATION AND FABRICATION OF NA1+XZR2SIXP3-XO12 [J].

QUON, DHH ;

WHEAT, TA ;

NESBITT, W .

MATERIALS RESEARCH BULLETIN, 1980, 15 (11) :1533-1539

[10] ZUM SCHWINGUNGSSPEKTRUM DER PHOSPHORSAURE .1. INFRAROT- UND RAMAN-SPEKTREN VON PHOSPHATLOSUNGEN [J].

STEGER, E ;

HERZOG, K .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1964, 331 (3-4) :169-182