MOLECULAR CONFIGURATION AND INTERACTIONS OF AMIDE GROUP .I. SOLVENT EFFECTS ON VIBRATIONAL FREQUENCIES

被引：59

作者：

CUTMORE, EA

HALLAM, HE

机构：

[1] Department of Chemistry, University College of Swansea, Singleton Park

来源：

SPECTROCHIMICA ACTA PART A-MOLECULAR SPECTROSCOPY | 1969年 / A 25卷 / 11期

关键词：

D O I：

10.1016/0584-8539(69)80205-9

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

The vibrational frequencies of a series of primary, secondary and tertiary amides and urethanes have been studied between 4000 and 650 cm-1 in a comprehensive range of solvents. The results are discussed in terms of the electronic effects in the -CO·NH-and -O·CO·NH- groups. Estimates are given for the pKa values of primary and secondary compounds. © 1969.

引用

页码：1767 / &

共 11 条

[1] INFRA-RED SPECTRA AND SOLVENT EFFECTS .2. CARBONYL ABSORPTIONS
BELLAMY, LJ
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[2] INFRA-RED SPECTRA AND SOLVENT EFFECTS .1. X-H STRETCHING FREQUENCIES
BELLAMY, LJ
HALLAM, HE
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[3] MICROWAVE SPECTRUM AND MOLECULAR STRUCTURE OF FORMAMIDE
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[5] INFRA-RED SOLVENT SHIFTS AND MOLECULAR INTERACTIONS .1. RELATIVE STRENGTHS OF PRIMARY AND SECONDARY NITROGENOUS BASES
CUTMORE, EA
HALLAM, HE
[J]. TRANSACTIONS OF THE FARADAY SOCIETY, 1962, 58 (469): : 40 - &
[6] SOLVENT EFFECTS ON THE INFRA-RED SPECTRA OF 2-NITROANILINES
DYALL, LK
[J]. SPECTROCHIMICA ACTA, 1961, 17 (03): : 291 - 299
[7] SOLVENT EFFECTS ON INFRA-RED SPECTRA OF ANILINES .3. ACETANILIDES
DYALL, LK
KEMP, JE
[J]. SPECTROCHIMICA ACTA, 1966, 22 (03): : 483 - &
[8] SOLVENT EFFECTS ON INFRA-RED SPECTRA OF ANILINES .2. N-METHYL- AND N-PHENYLANILINES
DYALL, LK
KEMP, JE
[J]. SPECTROCHIMICA ACTA, 1966, 22 (03): : 467 - &
[9] HALLAM HE, 1963, INFRARED SPECTROSCOP, pCH12
[10] JEWELL DJ, 1958, SPECTROCHIM ACTA, V13, P254

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