CONVENIENT SYNTHETIC ROUTE TO TRIPLE HALIDE BRIDGED ARENE COMPLEXES OF RUTHENIUM(II) AND OSMIUM(II)

被引：10

作者：

ARTHUR, T

STEPHENSON, TA

机构：

[1] Department of Chemistry, University of Edinburgh, Edinburgh

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 168卷 / 02期

关键词：

D O I：

10.1016/S0022-328X(00)83285-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Protonation with HBF4 of equimolar mixtures of [M(arene)X2(C5H5N)] and [M(arene)X(C5H5N)2]PF6 in methanol provides a convenient, high yield, synthetic route to the triple halide bridged arene complexes [M2(arene)2X3]BF4 (M = Ru; X = Cl, Br; arene = C6H6, 1,3,5-C6H3Me3; M = Os, X = Cl, arene = C6H6). © 1979.

引用

页码：C39 / C41

页数：3

共 4 条

[1]

ARTHUR T, UNPUBLISHED

[2] ARENE RUTHENIUM(II) COMPLEXES FORMED BY DEHYDROGENATION OF CYCLOHEXADIENES WITH RUTHENIUM(III) TRICHLORIDE [J].

BENNETT, MA ;

SMITH, AK .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1974, (02) :233-241

[3] DISPROPORTIONATION OF A HALOGEN-BRIDGED COMPLEX CONTAINING PLATINUM AND PALLADIUM [J].

KIFFEN, AA ;

MASTERS, C ;

VISSER, JP .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1975, (13) :1311-1315

[4] CATIONIC, NEUTRAL AND ANIONIC COMPLEXES OF RUTHENIUM(II) CONTAINING ETA-6-ARENE LIGANDS [J].

ROBERTSON, DR ;

STEPHENSON, TA ;

ARTHUR, T .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1978, 162 (01) :121-136

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