CIDNP AND INTERSYSTEM CROSSING IN BIRADICALS

被引：30

作者：

DOUBLEDAY, C

机构：

[1] Department of Chemistry, SUNY-Buffalo, Buffalo

来源：

CHEMICAL PHYSICS LETTERS | 1979年 / 64卷 / 01期

关键词：

D O I：

10.1016/0009-2614(79)87277-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Magnetic field dependence curves are presented for the 13C CIDNP signals resulting from photolysis of 2-phenylcycloalkanones in cyclohexane. One of the three biradical-derived products, the trapped ketene, reverses its polarization at high field. This is interpreted in terms of a competition between nuclear spin-dependent and nuclear spin-independent intersystem crossing in the biradical, and as evidence for a product selectivity based on the mechanism of intersystem crossing. © 1979.

引用

页码：67 / 70

页数：4

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[No title captured]

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