C-13 NMR RELAXATION STUDY ON MOLECULAR-MOTION OF N-ALKANE CHAINS IN THE ROTATOR PHASE

被引：10

作者：

ISHIKAWA, S

ANDO, I

机构：

[1] TOKYO INST TECHNOL,DEPT POLYMER CHEM,MEGURO KU,TOKYO 152,JAPAN

[2] KAO RES LABS,ICHIKAI,TOCHIGI,JAPAN

来源：

JOURNAL OF MOLECULAR STRUCTURE | 1992年 / 273卷

关键词：

D O I：

10.1016/0022-2860(92)87088-D

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The C-13 spin-lattice relaxation times (T1s) of n-C32H66 were measured in the crystalline state, rotator phase and melting state, in order to clarify the molecular motion of the rotator phase. From these results it was found that in the rotator phase every methylene carbon has almost the same value of T1. This indicates that all-trans zigzag chains in the rotator phase rotate rapidly about their long axes.

引用

页码：227 / 232

页数：6

共 7 条

[1] RELAXATION EFFECTS IN NUCLEAR MAGNETIC RESONANCE ABSORPTION [J].