ELECTROCHEMICAL NOISE-ANALYSIS OF IRON EXPOSED TO NACL SOLUTIONS OF DIFFERENT CORROSIVITY

被引:175
作者
MANSFELD, F
XIAO, H
机构
[1] Corrosion and Environmental Effects Laboratory (CEEL), Department of Materials Science and Enqineering, University of Southern California, Los Angeles
关键词
12;
D O I
10.1149/1.2220796
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Potential and current noise data have been collected for pure iron foils which were exposed to 0.5N NaCl which was aerated, deaerated, or aerated with NaNO2 added as inhibitor. Data were obtained at the beginning of each hour over a 24 h period. The noise data were displayed as power spectral density plots or as the rms values of potential (deltaV) and current (deltaI). The potential noise data seem to be affected by fluctuations of mass transport and did not agree with the known corrosion behavior of the systems under investigation. However, good agreement was observed for the current noise data. For the noise resistance R(n) = deltaV/deltaI similar values as for the polarization resistance R(p) determined with EIS at the end of the tests were obtained. The pit index defined by others as PI = deltaI/I(mean), where I(mean) is the mean current in a noise measurement, did not provide meaningful information. The experimental data obtained in this investigation have been compared with those reported previously by Lumsden et al.
引用
收藏
页码:2205 / 2209
页数:5
相关论文
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