THE OXENOID CHARACTER OF METALATED HYDROPEROXIDES O(M)OR - OXIDATION OF ORGANOMETALLIC COMPOUNDS R'M' TO R'OH UNDER MILD CONDITIONS

被引：29

作者：

BOCHE, G

BOSOLD, F

LOHRENZ, JCW

机构：

[1] Fachbereich Chemie, Universität Marburg

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1994年 / 33卷 / 11期

关键词：

D O I：

10.1002/anie.199411611

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The oxygen analogues of carbenoids 1 and nitrenoids 2, namely the lithiated hydroperoxides 3, are more electrophilic than the corresponding nonlithiated derivatives. These “oxenoids” can convert organometallic compounds R′M′, including cuprates, into alcohols under mild conditions. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1161 / 1163

页数：3

共 52 条

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