LONG-RANGE COUPLING IN CYCLOHEXANE FRAGMENTS

被引：12

作者：

CAREY, PR

DITCHFIELD, R

机构：

[1] The Chemical Laboratory, University of Sussex, Brighton, BN1 9QJ, Falmer

来源：

MOLECULAR PHYSICS | 1968年 / 15卷 / 05期

关键词：

D O I：

10.1080/00268976800101411

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Couplings over four bonds, 4JHH, are discussed for compounds where stereochemistry is thought to be the dominant factor determining their values. A simple MO theory [3, 4] provides calculated coupling constants in agreement with experiment. The form of the theory permits an analysis of the mechanisms responsible for long-range coupling. The approach is generalized to include distorted cyclohexane fragments and these results are presented in a graphical form. © 1968 Taylor and Francis Group, LLC.

引用

页码：515 / +

页数：1

共 12 条

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[9] RELATIVE IMPORTANCE OF DELOCALIZATION TERMS IN PROTON SPIN-SPIN COUPLING CONSTANTS
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[10] VIRTUAL LONG-RANGE SPIN-SPIN COUPLINGS IN NMR - LINEAR 3-SPIN SYSTEM AND QUALITATIVE IMPLICATIONS OF HIGHER SYSTEMS
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