REACTION OF URANIUM OXIDES WITH ALKALI HALIDES

被引：15

作者：

ALLPRESS, JG

ANDERSON, JS

HAMBLY, AN

机构：

[1] Department of Chemistry, University of Melbourne

来源：

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY | 1968年 / 30卷 / 05期

关键词：

D O I：

10.1016/0022-1902(68)80545-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of the oxides UO3 and U3O8 with excess alkali halides MX, particularly KCl, RbCl and CsCl, have been studied using techniques of i.r. spectroscopy and X-ray diffraction. The final product of these reactions is always the diuranate M2U2O7, but several intermediate phases have been detected and identified. These phases have the compositions MxUO3Clx (x ∼ 0·8) and M4U5O16Cl2. Some of the properties of these compounds are described, and the mechanism of the reaction is discussed. © 1968.

引用

页码：1195 / &

共 19 条

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