THE PARTIAL OXIDATION OF ETHANE OVER A B2O3-AL2O3 CATALYST

被引：44

作者：

MURAKAMI, Y ^{[1
]}

OTSUKA, K ^{[1
]}

WADA, YJ ^{[1
]}

MORIKAWA, A ^{[1
]}

机构：

[1] TOKYO INST TECHNOL, DEPT CHEM ENGN, MEGURO KU, TOKYO 152, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1990年 / 63卷 / 02期

关键词：

D O I：

10.1246/bcsj.63.340

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The catalytic activities were examined for the partial oxidation of ethane over various metal oxides. B2O3(30wt%)-added Al2O3 showed the highest catalytic activity in the formation of acetaldehyde (yield: 1.03%) and ethylene (14.6%). Ethylene and acetaldehyde are assumed to be formed via a common reaction intermediate because of the similarity in their kinetic behavior and the similar activation-energy values observed. The second-order dependence of the formation rates for the two products on the pressure of ethane suggests that the two molecules of ethane participate in the formation of the intermediate in the chain reaction mechanism proposed. The active site for the formation of acetaldehyde from the intermediate is suggested to be a highly dispersed boron electron-donated from alumina, but that for ethylene must be different from that of acetaldehyde.

引用

页码：340 / 346

页数：7

共 19 条

[1] KINETICS AND MECHANISM OF OXIDATIVE DEHYDROGENATION OF ETHANE AND SMALL ALKANES WITH NITROUS-OXIDE OVER COBALT-DOPED MAGNESIUM-OXIDE [J].